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W.S. Winston Ho Laboratory

W.S. Winston Ho Laboratory

Molecular and chemical membrane separations; hydrogen purification; CO2 capture; water desalination; antibiotic recovery; wastewater metal recovery

About

The Ho Lab specializes in membranes and separations including polymer and liquid membranes, carbon dioxide capture, hydrogen purification, fuel cell fuel-processing and membranes, facilitated transport, supported liquid membranes, reverse osmosis, gas treating, and pervaporation.  

Professor Ho is an expert in molecularly-based separations including definition of approaches, design of practical systems, scale-up and commercialization. 

Ho speaking with two students next to equipment
Professor Ho with researchers working on his membrane-fabrication equipment.

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Research

The research in Professor Ho’s group is on new membranes and materials for energy, environmental and biochemical applications, including CO2 capture from flue gas in power plants, H2 purification for fuel cells and from syngas, supported liquid membranes with strip dispersion for environmental and biochemical applications, water purification, and fuel-cell membranes. 

CO2 Capture from Flue Gas in Power Plants

Professor Ho and his students and researchers have synthesized and demonstrated novel amine-containing membranes capable of possessing both high CO2 permeability and CO2/N2 selectivity at relatively high temperatures (> 57oC) for CO2 capture from flue gas in coal- and natural gas-fired power plants.  The membranes are based on the facilitated transport mechanism, in which CO2 transport through the membrane is enhanced via reversible reaction with amine whereas N2 is rejected due to the absence of reaction in the membrane.  His group has elucidated the unusual phenomenon of both permeability and selectivity increases with temperature.  They have also demonstrated and elucidated the effect of amine steric hindrance in the solid membrane, showing significant enhancement for CO2 transport.  Moreover, they have shown the membranes stable to 1 – 5 ppm SO2 and NOx in real flue gas.  The membranes have exhibited an exceptionally high CO2/N2 selectivity of > 150, combined with a very high CO2 permeance of > 3500 GPU, achieving the highest combined performance.  One of the membranes is being scaled up and demonstrated at 1 MWe scale (20 tonne/day CO2) with commercial-size 8′′-diameter modules toward commercialization for flue gas CO2 capture with support of ~$15 million to Ohio State and its partners from DOE, American Electric Power, and Ohio Development Services Agency.  This membrane can capture CO2 at a lower cost than ever before.

H2 Purification for Fuel Cells and from Syngas

His group has tuned the novel amine-containing membranes to possess both high CO2 permeability and CO2/H2 selectivity at relatively high temperatures (100 – 180oC) for H2 purification for fuel cells and from synthesis gas.  They have demonstrated the removal of H2S to <10 ppb in the treated synthesis gas needed for water-gas-shift (WGS) reaction as H2S deactivates commercially available WGS catalysts.  They obtained < 10 ppm CO in the H2 product with a WGS membrane reactor using the membrane to drive the WGS reaction to the product side via CO2 removal.  The data were in good agreement with the prediction of their non-isothermal model.  They have also investigated the membranes for hydrogen purification in conjunction with solid oxide fuel cells for zero carbon electricity generation.  Furthermore, investigation of the membranes for the removal of CO2 and H2S from coal-derived synthesis gas at a relatively high pressure of ~35 atm, i.e., in integrated gasification combined cycle (IGCC), is in progress with funding from DOE and Ohio Development Services Agency.  Extending the membrane applicability to high-pressure separations including natural gas sweeting is underway.   

Other Separations

The investigation of CO2-selective membranes for other separations is underway.  The other separations include the removal of CO2 and H2S from syngas and biogas as well as CO2 from confined space air.

Tiles

Changlong Zou works on membrane coating
Membrane Coating
Ho Lab-Membrane Element Fabrication
Membrane Element Fabrication
Ho Lab-Wrapping FRP to element
Wrapping FRP
side view
Membrane Element

From Membrane To Membrane Element

Large-scale membrane fabrication machines

Roll-to-roll coating/casting machine
Roll-to-roll continuous coating machine
casting machine
Large-scale continuous casting machine

Membrane module fabrication station

wrap
Membrane element fabrication station
frp
FRP wrapping station

Member List

Announcements

News
Novel membrane technology aims to cut industrial greenhouse gas emissions
DOE invests $12M in novel membrane technology that captures carbon emissions
Research of graduate students receives national support
Students recognized at Lowrie Awards Banquet
Ho and Joshi named Innovator of the Year finalists
Graduate students win 2023 Elias Klein Founders’ Travel Supplement Awards
2022 Graduate Research Symposium another resounding success
Department announces student award honorees

Publications